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Arsenal qualified for the Champions League by finishing as runner-up to Manchester United in the Premier League of 1999/2000.   

   
Champions League First Group Stage
Group B Tue Sep 12 Sparta Prague (Czech Republic) Away Won 1-0
Group B Wed Sep 20 Shakhtar Donetsk (Ukraine) Home Won 3-2
Group B Wed Sep 27 Lazio (Italy) Home Won 2-0
Group B Tue Oct 17 Lazio Away Drew 1-1
Group B Wed Oct 25 Sparta Prague Home Won 4-2
Group B Tue Nov 7 Shakhtar Donetsk Away Lost 0-3
Arsenal won the Group and qualified for the second Group stage.   Full Group results and table.
Champions League Second Group Stage
Group C Wed Nov 22 Spartak Moscow (Russia) Away Lost 1-4
Group C Tue Dec 5 Bayern Munich (Germany) Home Drew 2-2
Group C Tue Feb 13 Lyon (France) Away Won 1-0
Group C Wed Feb 21 Lyon Home Drew 1-1
Group C Tue Mar 6 Spartak Moscow Home Won 1-0
Group C Wed Mar 14 Bayern Munich Away Lost 0-1
Arsenal finished second in the Group and qualified for the Quarter-Finals.   Full Group results and table.
Quarter-Final
1st Leg Wed Apr 4 Valencia (Spain) Home Won 2-1
2nd Leg Tue Apr 17 Valencia Away Lost 0-1
Lost on away goals after finishing 2-2 on aggregate.